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General Silver Forum Silverplate is a Siver Alloy ?
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Author | Topic: Silverplate is a Siver Alloy ? |
T-Bird-Art Posts: 143 |
posted 10-27-2003 04:26 PM
Just heard an expert , on "Antique Roadshow" say that pure Silver is like Gold--it does not tarnish . So what is commonly referred to as Silverplate? It must not be pure Silver. Every piece I have is tarnished. [This message has been edited by T-Bird-Art (edited 10-28-2003).] IP: Logged |
Scott Martin Forum Master Posts: 11520 |
posted 10-27-2003 05:12 PM
This brings to mind that old saying... Those who can, do. Whatever the source of information (i.e., books, magazines, TV, radio, Internet "experts", the Silver Salon Forums) it is always best to seek confirmation from more than one resource. Just make sure that the different resources aren't all quoting the same source or folklore.
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Dale Posts: 2132 |
posted 10-27-2003 06:08 PM
In the US, silverplate ordinarily refers to electo-plated pieces. The usage in other parts of the world varies. What this means is that pure silver is electrically bonded to another metal. The process involves immersing the item in heated cyanide, running currents through the cyanide and other things you should not do in your kitchen. The surface of a plated piece will tarnish in the presence of sulfer. Prior to about 1500 ce, silver did not tarnish much, which tells us something about air pollution build up. Tarnish can also occur due to problems with water used in cleaning it, and some other things. Did the roadshow expert also say that the item which languishes in shops at $40 would bring thousands at auction? IP: Logged |
Anuh Posts: 190 |
posted 10-27-2003 08:17 PM
Yes and no, Dale. Some firms plated with sterling silver rather than pure silver, which is also where some of the confusion about silver/silverplate arises. But you are right, in that MOST platers seem to have plated with pure silver, the depth of the plating varying with a lot of other factors, mostly (I believe) how much they could charge for it after plating and how well that price would sell. I'm surprised at how much some of my sterling items, in my stock room, have NOT tarnished, and how much some OTHER sterling pieces have, which may be in part due to the exact content of the sterling as much as anything. And yes, sulfur does badly tarnish silver. Propane gas leaking into a kitchen will also cause any pieces in that room to tarnish badly, and can be used as a means of finding out if you have a tiny leak in your stove. I assume natural gas would do the same, and in both cases, I assume it must be a sulfur component of the gas that does it. If I'm wrong in that, I would certainly love to find out what it is. But believe me, I know it happens, so I try to avoid keeping any silver anywhere near my kitchen, since we experience small leaks when the tank gets low. ;-D ------------------ IP: Logged |
Arg(um)entum Posts: 304 |
posted 10-27-2003 09:16 PM
" Some firms plated with sterling silver rather than pure silver..." Anuh, are you saying that they electroplate with an alloy? I had been under the impression that electroplating always involves a pure element. Some of the variation that you notice on different item may be attributable to different compositions of the alloy but I wonder whether the quality or let's say the method of finishing doesn't play a major role. It is one of the aspects never or rarely discussed in these forums that manufacturers' finishing may vary considerably. I know little about this but I seem to remember reading about "white boiling", "pickling", etc. IP: Logged |
adelapt Posts: 418 |
posted 10-28-2003 04:31 AM
The term "sterling silver plated" on EP wares means, I think, very little. The plating would be normal 'pure' silver plating, but since the market has been taught the virtues of sterling silver (which is only a minimum standard of 925/1000) that term is used as a familiar and reliable one. It is also more likely that new sterling items were silver plated because that conceals solder lines and suchlike, rather than for tarnish prevention. It is a problem if you need repairs to the things and apply heat though, as the usually unsuspected plating can bubble messily. IP: Logged |
Arg(um)entum Posts: 304 |
posted 10-28-2003 09:58 AM
I should have specified that the references I saw about electroplating solid silver were about flatware though the idea of plating holloware in order to enhance the appearance of seams and the likes does make sense. Also, rechecking the one note that I had saved, this one speaks of plating the items in order to improve surface quality (presumably hardness). [This message has been edited by Arg(um)entum (edited 10-28-2003).] IP: Logged |
Dale Posts: 2132 |
posted 10-28-2003 12:06 PM
From my limited experience at plateing things, I would say that holloware is not a good candidate for the process. The problem is the joins, seams and solder joints are of a different metal than the piece itself. Becuase of this, they may not carry the current to the adjoining piece. This is why it is not unusual to find items where some parts are thouroughly plated and other parts are not. The solutions to this problem are many, but add considerable to cost. The problem the plater faces is having an item that will carry the current uniformly over the item. On flatware, which tends to be one piece construction, this is not a big issue. Holloware is frequently assembled from a number of pieces. The joins are where the plater runs into issues. If something has been resoldered, there may be different solder which have slightly different conductivities resulting in a non uniform deposit. The obvious solution is to take the item apart and plate each piece individually. But that involves dealing with old solders. And trying to resolder, which has a spefic problem: many older pieces have metal with a melting point lower than that of modern solders. And it is unknown which parts of the item have that problem and which do not. Our old friend 'white metal mounts' may have a slightly different conductivity from the main piece. Anyway, this is part of the difficulty of plateing hollow ware. IP: Logged |
Anuh Posts: 190 |
posted 10-28-2003 07:20 PM
Arg & Adelpt: My information on the process of plating with sterling comes from Reed & Barton during a tour with a group of students I took through there many years ago. The man who took us around (who I believe was the Plant Manager, but don't hold me to it) said that during the war years (both WW), people who turned in their silver for recycling wanting to help the war effect helped supply their need for silver to plate objects. He said they sometimes would use the sterling objects as was, rather than melted down, as the source of silver for the plating process. I didn't think to ask at that time, but would it be possible that using the sterling left a residue of the alloyed metals behind? That's just a thought that hits me. If the information IS incorrect, I at least got it from what should have been a reliable source. The process of plating sterling with pure silver was not mentioned at this time, but... It one sence it makes sense, but in others it does not since it would increase the cost. I do know that Stieff did not do so and the process of cleaning silver was something we did regularly in the store. We used a dip TSP (got it right this time) in an aluminum bucket of hot water and then hand-dried with soft cloths. The pieces were done often enough to just require a dip to remove the light tarnish that occurred. As for other forms of finishing that might prevent the tarnish, the only thing I know of is the "varnish" finish some cheap manufacturers put on to try to keep it out. Unfortunately, I've always found that on silverplate and usually the pieces are badly mottled with tarnish in spots where the "varnish" had cracked and let air in. And it is extremely hard to get rid of. As for the market being taught to revere "sterling" over silverplate, one of the greatest things I can say is that the average person no longer seems to know the difference, if they ever did. I've bought many a piece of marked sterling in various locales in this country for no more and often less than I would pay for silverplate! Strange, but true. Dale: Thanks for that information on plating. It is something I wish we could do more easily, as it would recoup many a piece of badly worn flatware that has an age/design value to the collectors of it but who can't afford to get it replated one piece at a time. I've seen some pieces of flatware that have been done with great success - but it requires removing the old silver to remove nicks, worn spots, etc. When replated that way, it looks like new. ------------------ IP: Logged |
Paul Lemieux Posts: 1792 |
posted 10-28-2003 08:58 PM
quote: Have you checked to see if those that do not tarnish are covered with a protective lacquer? I know this was not uncommon on some 20th century silver. Also it is not unprecedented to find high quality older silver with lacquer. For example, a Durgin 1880s serving fork and the silver applied decoration on a copper vase had both been lacquered when I purchased them. I removed the lacquer with simple nail polish remover (acetone) and then gently hand polished the silver with a rouge cloth. It was not a fun task on the mixed metal vase. However, I don't know if I would recommend going around de-lacquering pieces that were originally made that way and are still mint. But as the fork and vase was not originally lacquered, I did not want the finish on there anymore. Sometimes lacquered pieces will have bits of the lacquer missing, which results in uneven tarnish spots. I have cleaned one such, a mid-20th century low quality compote. It had about half of its coating gone. So the exposed silver tarnished as normal silver does, and the rest of the lacquer had yellowed slightly. After removing the rest of the lacquer, I polished the entire piece with Simichrome and Wright's silver cream until it had an even finish. I don't know if it was worth going through this process considering the small value piece (probably barely more than the cost of the Simichrome I used ). IP: Logged |
Paul Lemieux Posts: 1792 |
posted 10-28-2003 09:00 PM
It looks like it took me so long to write my post that Anuh beat me to the point about flaking lacquer on silver. IP: Logged |
Arg(um)entum Posts: 304 |
posted 10-29-2003 06:12 PM
"some of the "facts" being used in some of the more recent posts." I feel 'touché', so let me correct and add some details to my comment re. the properties of silverplated surfaces. In the main they are based on a 1960's book on German flatware (Klein, W.: Bestecke und was dazu gehört). I do not have the book but I copied some pages relevant to what interested me at the time I had access to it (the meaning of the "90" standard for silverplating). I remember being surprised at a statement that most solid silver flatware was being finished by plating - as it wasn't what I was focused on I did not grab that page. The part that I do have contains a discussion of a term "Hartglanz" as it applies to plated ware. It relates that this (then) new process results in a much tougher surface with a hardness as high as "210 kp/MM2 Vickers". It also states that this process is slightly more expensive than regular plating but results in merchandise with greater resistance to abrasion. The regulation in question permits the use of the term "Hartglanz" and equivalent ones in labeling and advertising only if the main pieces can meet a Vickers Hardness test of "130 kg/mm2". I won't attempt to understand the Vickers standard or how these numbers relate to those quoted for pure silver and various alloys (quoted in some form of Vickers as well as Brinell). So I'll just leave it that there is a process that considerably enhances the surface of plated ware and that also improves the surface of solid silver articles. In translating the term HARTGLANZ, 'Hart' is the easy part , 'Glanz' can mean all of gloss, shine, brightness, etc. WMF on its website translate it simply as 'hardplated', to quote: "To protect the surface, all WMF pure silver ranges(!) are additionally hard silverplated." (they do mean flatware!) So how relevant is this? I believe that whenever one company makes a usefull improvement to a product sooner rather than later others catering to the same market segment follow it. There is no reason to believe that top companies in the US or elsewhere wouldn't have adopted some variation of this improvement. With respect to solid silver, they like many European companies, may have chosen not to emphasize it in their marketing out of fear of confusing their potential clientele. For those who are mainly interested in much older items this doesn't mean much although it can serve as a reminder that surface treatment will have varied from one maker to another specially in an earlier age when innovation didn't travel quite as fast as today. [This message has been edited by Arg(um)entum (edited 10-29-2003).] IP: Logged |
Anuh Posts: 190 |
posted 10-29-2003 07:35 PM
quote: You raised some excellent points, Paul. I couldn't think of the word lacquer for all the world when I was writing my post - Flabby Brain Syndrome strikes again! ;-D The pieces that have tarnished the least are ones that I polished myself with Simichrone, mostly from a heavily tarnished state. So I'm quite sure that there was no lacquer coating on them at that time. Other pieces which I have polished myself have retarnished and in some cases quite noticeably. So I DO see a difference in the tarnishing quality of sterling pieces. One thing I may look at the next time I go in there is if there is a discernible difference between makers. That would support my feeling that it must be, in part, a difference in the exact composition of the sterling. ------------------ IP: Logged |
T-Bird-Art Posts: 143 |
posted 11-02-2003 04:54 PM
Thanks for all the answers from the Big Guns in this Forum. I feel like a bale of Hay has just been dropped on me ! Seriously, it was refreshing to re-visit our roots. What amazes me is how in the world 1800's silversmiths sifted thru all the molecular chemistry when 99.5% of the population didn't know what molecule was. IP: Logged |
Dale Posts: 2132 |
posted 11-03-2003 12:13 PM
Lacquer is not the only thing one can find on silver. There are other substances put on by amateurs. Acrylic floor wax is one favored by many antique dealers; it is pain and agony to get off. Then there is the caterers solution: shrink wrapping saran wrap on trays. A great deal of time and effort goes into figuring out what idiot things have been done to each piece. IP: Logged |
Vi Posts: 17 |
posted 11-05-2003 12:55 PM
quote: I hesitate to add to the excellent responses from experts, but your original question seems so simple to me that I'd like to offer a simple answer. Silver tarnishes. Sterling tarnishes. Silverplate tarnishes because there is sterling/real silver applied to a base metal and being exposed to the air causes silver to tarnish. Gas heat and salt water air may be the biggest villans in the tarnish war. In my silver shop, I don't notice much difference in how silverplated items tarnish vs sterling pieces. We carry both sterling and silverplate in approximately equal amounts I certainly agree with Scott's Roadshow comment. My recommendation about laquering is don't do it. Fine antique silverplate stays beautiful for 50-100 years if properly hand polished. Don't laquer sterling either. It stops the beautiful patination from years of love and use. When your silver gets "yellow" enough to bother you, polish it. It deserves it! Vi IP: Logged |
T-Bird-Art Posts: 143 |
posted 01-16-2004 06:10 AM
Just curious. You silversmiths get silver in bulk , presumably in a small block. Do these blocks tarnish like silverplated hollowware when they sit around for 6 mos + ? IP: Logged |
Dale Posts: 2132 |
posted 01-16-2004 11:23 PM
Yes, they tarnish when they sit around. All the time. IP: Logged |
T-Bird-Art Posts: 143 |
posted 02-17-2004 01:23 PM
More Silver information just found: " Chemically silver is not very active and does not react with oxygen or water at ordinary temperatures. Sulfur and sulfides tarnish silver and is caused by the formation of silver sulfide on the surface of the metal. Eggs, which contain a considerable quantity of sulfur as a constituent of protein, tarnish silver extremely quickly. Small amounts of sulfide, which occurs naturally in the atmosphere and which, as hydrogen sulfide (H2S), is added to natural gas used domestically, tarnish silver." IP: Logged |
FredZ Posts: 1070 |
posted 02-17-2004 02:13 PM
I often have to explain to folks that silver does not "oxidize" but instead "sulfides". Everytime I eat eggs with my silver forks I have to remove the tarnish from the tines. Sulfur is an ingedient in the making of rubber bands and that is why you never wrap your spoons or any silver item with rubber bands. Fred IP: Logged |
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